| Product name : | ENGEN DIESEL |
| Chemical name : | Diesel fuel |
| Synonyms : | Hydrocarbon Liquid |
| Product use : | Automotive diesel fuel |
| UN number : | 1202 |
| Supplier : | Engen Petroleum Limited (Tel: 021-403 4911, a/h: 021-403 4099) |
| Health Emergency Telephone : | 021-658 5111 (Red Cross Poison Service) |
| Transport Emergency Telephone : | 011-975 1278/83 (Hazchemwise) |
| Customer Service Center : | 0860 036 436 (Sales and Technical Information) |
| MSDS Internet website : | www.engen.co.za/content/products/default2.htm |
2. COMPOSITION/INFORMATION ON INGREDIENTS
| Chemical name | CAS-No. | Weight% | Symbol Codes | R-Phrase Numbers |
| Diesel fuel | 68334-30-5 | > 98.00 | Xn, N | R40, R51/53, R65, R66 |
| Ethyl Benzene | 100-41-4 | > 1.00 | Xn | R20, R45 |
| Naphthalene | 91-20-3 | > 1.00 | R45 |
See Section 15 for European Label Information.
See Section 8 for Exposure Limits (if applicable).
3. HAZARDS IDENTIFICATION
| Emergency response data : | Light Amber Liquid. Flammable. Product can accumulate a static charge and release vapours which may cause a fire or explosion. DOT ERG No. : 128 |
| Potential health effects | |
| Inhalation : | Respiratory irritation, dizziness, nausea and loss of consciousness. In cases of extreme exposure death is possible. Diesel exhaust may cause lung cancer. |
| Skin : | Irritation or more serious skin disorders. Note: This product may contain polycyclic aromatic hydrocarbons, some of which have been reported to cause skin cancer in humans under conditions of poor personal hygiene, prolonged repeated contact, and exposure to sunlight. |
| Eye : | Irritant. |
| Ingestion : | Low viscosity material if swallowed may enter the lungs and cause lung damage. |
| Potential environmental effects : | Toxic to fish, aquatic organisms and wildlife. Do not discharge into lakes, streams, ponds and ground water supply. |
See Section 11 for further health effects/toxicological data.
4. FIRST AID MEASURES
| Inhalation : | Remove from further exposure. If respiratory irritation, dizziness, ENGEN DIESEL 2 nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with mechanical device or use mouth-to-mouth resuscitation with a mouthpiece. |
| Skin contact : | Remove contaminated clothing. Dry wipe exposed skin and cleanse with hand cleaner, soap and water. Launder contaminated clothing before reuse. (See Section 16 – Injection Injury) |
| Eye contact : | Flush thoroughly with water for at least 15 minutes. Get medical assistance. |
| Ingestion : | Seek immediate medical attention. Do not induce vomiting. |
| Note to doctors : | Material if aspirated into the lungs may cause chemical pneumonitis. Skin contact may aggravate an existing dermatitis. Treat appropriately. |
5. FIRE-FIGHTING MEASURES
| Extinguishing media : | Carbon dioxide, foam, dry chemical and water fog. |
| Special fire fighting procedure : | Water spray should only be used to keep fire-exposed containers cool, flush spills away from exposures, disperse vapours and protect personnel attempting to stop leak. Prevent runoff from fire control or dilution from entering streams, municipal sewers, or drinking water supply. |
| Special protective equipment for firefighters : | For fires in enclosed areas, fire fighters must use Self-Contained Breathing Apparatus. |
| Products of decomposition : | Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. |
| Flash Point : | >55 °C (ASTM D-93) |
| Upper Explosion Limit : | 7 %(V) |
| Lower Eplosion Limit : | 0.6 %(V) |
| NFPA Hazard Id : | Health: 1; Flammability: 2; Reactivity: 0 |
6. ACCIDENTAL RELEASE MEASURES
| Procedure if material is released or spilled : | Report spills/releases as required to appropriate authorities. |
| Methods for cleaning up : | Eliminate sources of ignition. Warn occupants and/or ships in the downwind areas of fire and explosion hazard, and warn them to stay clear. |
| LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping using explosion-proof equipment or contain spilled liquid with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of absorbed residues as directed in Section 13. | |
| WATER SPILL: Notify port and relevant authorities. Confine with booms if skimming equipment is available to recover the spill for later recycling or disposal. If permitted by local authorities and environmental agencies disperse in unconfined waters. If allowed by regulatory authorities the use of suitable dispersants should be considered where recommended in local oil spill procedures. | |
| Personal precautions : | See Section 8. |
| Environmental precautions : | Prevent spill from entering municipal sewers, water sources or low lying areas. Advise the relevant authorities if contaminations have occurred. |
7. HANDLING AND STORAGE
| Safe handling advice : | Keep product away from high energy ignition sources, heat, sparks, pilot lights, static electricity, and open flames. Harmful in contact with or if absorbed through the skin. Avoid inhalation of vapours or mists. Use in well ventilated area away from all ignition sources. |
See Section 8 for additional personal protection advice when handling this product.
| Storage information : | Store away from all ignition sources in a cool, well ventilated area. This product is a static accumulator, therefore, all storage containers should be grounded and bonded. Drums should also be equipped with self-closing valves, pressure vacuum bungs and flame arresters. |
| Storage and handling procedures : |
Electrical equipment and fittings must comply with local fire prevention regulations for this class of product. Refer to national or local regulations covering safety at petroleum handling and storage areas for this product. |
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational Exposure Limits (OELs)
| Components | CAS-No. | Source | TWA | Value | Notations | |
| Naphthalene | 91-20-3 |
ACGIH TLV |
LTEL | 52 mg/m3 | 10 ppm | Skin; A4 |
| STEL | 79 mg/m3 | 15 ppm | ||||
| OSHA PEL | LTEL | 50 mg/m3 | 10 ppm | |||
| STEL | 75 mg/m3 | 15 ppm | ||||
| Diesel fuel | 68334-30-5 | ACGIH TLV | LTEL | 100 mg/m | 315 ppm | Skin; A3 |
| Ethyl Benzene | 100-41-4 | ACGIH TLV | LTEL | 434 mg/m3 | 100 ppm | A3; BEI |
| STEL | 543 mg/m3 | 125 ppm | ||||
| OSHA PEL | LTEL | 435 mg/m3 | 100 ppm | |||
| STEL | 545 mg/m3 | 125 ppm | ||||
STEL: Short Term Exposure Limits – Time Weight Average (TWA) over 15 Minutes
Note: Limits Shown for guidance only. Follow applicable regulations.
Personal Protection Equipment (PPE)
| Engineering controls : | Use in well ventilated area. Explosive-proof ventilation equipment with local exhaust is desirable. |
| Respiratory protection : | Approved respiratory equipment must be used when airborne concentrations are unknown or exceed the recommended exposure limit. Self-Contained Breathing Apparatus may be required for use in confined or enclosed spaces. |
| Eye protection : | If splash with liquid is possible, chemical type goggles should be worn. |
| Skin and body protection : | Impervious gloves must be worn. If body contact is likely, appropiate personal protective equipment must be worn. Good personal hygiene practices should always be followed. |
9. PHYSICAL AND CHEMICAL PROPERTIES
| Appearance : | Liquid. |
| Colour : | Light Amber |
| Odour : | Hydrocarbon |
| Solubility : | Negligible |
| Boiling point/range : | 88 °C |
| Flash Point : | > 55 °C (ASTM D-93) |
| Vapour pressure : | 0.5 hPa |
| Relative vapour density : | 2 |
| Density : | 0.8450 g/cm3 @ 20 °C |
| Pour point : | <-7 °C |
| Viscosity, kinematic : | 3.5 mm2/s @ 40 °C (ASTM D-445) |
| < 1 mm2/s @ 100 °C (ASTM D-445) |
10. STABILITY AND REACTIVITY
| Stability : | Stable. |
| Conditions to avoid : | Extreme heat and high energy sources of ignition, such as sparks and static electricity. |
| Materials to avoid : | Halogens, strong acids, alkalis and oxidizers. |
| Hazardous decomposition products : | Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. |
11. TOXICOLOGICAL INFORMATION
| Acute oral toxicity : | (Rats): Practically non-toxic (LD50: Greater than 2000 mg/kg). Based on testing of similar products and/or components. |
| Acute inhalation toxicity : | (Rats): Practically non-toxic (LC50: greater than 5mg/l). Based on testing of similar products and/or the components. |
| Acute dermal toxicity : | (Rabbits): Practically non-toxic (LD50: greater than 2000 mg/kg). Based on testing of similar products and/or the components. |
| Skin irritation : | (Rabbits): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. |
| Eye irritation : | (Rabbits): Practically non-irritating. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. |
| Sensitization : | Middle distillate oils were not skin sensitizers when tested in a Modified Buehler Guinea Pig Sensitization Assay. |
| Repeated dose toxicity : | Repeated dermal application of middle distillates, heating oils and diesel oils to rabbits for 2-4 weeks at up to 1 gm/kg resulted in strong to severe skin irritation with some weight loss at the higher dose. Toxic effects ranging from weight loss to mortality was observed in rabbits treated repeatedly with very high doses (6 gm/kg) of these oils. Repeated inhalation exposure of middle distillate and diesel vapour and aerosol to rats for 2-4 weeks at up to 6 mg/l resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and some reduction in lung function. |
| Teratogenicity : | Diesel fuel vapours were tested in an inhalation teratology (developmental toxicity) study in rats and when only minimal maternal toxicity was observed, no fetotoxic or developmental effects were observed. A developmental toxicity study of dermally applied middle distillates did indicate fetotoxicity (reduced litter size, litter weight, increased resorptions) at doses that also caused significant maternal toxicity. |
| Carcinogenicity : | Diesel fuel vapours were tested in an inhalation teratology (developmental toxicity) study in rats and when only minimal maternal toxicity was observed, no fetotoxic or developmental effects were observed. A developmental toxicity study of dermally applied middle distillates did indicate fetotoxicity (reduced litter size, litter weight, increased resorptions) at doses that also caused significant maternal toxicity. |
| Other toxicological information : | Overexposure to diesel exhaust fumes may result in eye irritation, headaches, nausea, and respiratory irritation. Animal studies involving lifetime exposure to high levels of diesel exhaust have produced variable results, with some studies indicating a potential for lung cancer. Limited evidence from epidemiological studies suggest an association between long-term occupational exposure to diesel engine emissions and lung cancer. Diesel engine exhaust typically consists of gases and particulates, including carbon dioxide, carbon monoxide, nitrogen compounds, oxides of sulphur, and hydrocarbons. Diesel exhaust composition will vary with fuel, engine type, load cycle, engine maintenance, tuning and exhaust gas treatment. Use of adequate ventilation and/or respiratory protection in the presence of diesel exhaust is recommended to minimize exposures. This product contains ethylbenzene. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and classified it as possibly carcinogenic to humans (Group 2B) based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans. |
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
| Biodegradability : | The majority of the components in this product would be expected to be inherently biodegradable. The constituents of diesel fuels which are volatilized will photodegrade in the atmosphere. The less volatile, more water-soluble components which are aromatic hydrocarbons will also undergo aqueous photodegradation. |
| Physico-chemical removability : | Dissolution of the higher molecular weight hydrocarbon components in water will be limited, but losses through sediment adsorption may be significant. |
| Bioaccumulation : | Not established. |
| Ecotoxicity effects | |
| Toxicity to fish : | This substance has also been shown to be toxic to specific fish species (LL50 = 1-10 mg/l for rainbow trout, Atlantic silverside). |
| Toxicity to aquatic organisms : | Based on test results for similar products, this substance may to toxic to aquatic organisms such as algae and daphnia (EL50/IrL50 = 1-10 mg/l). |
| Further information on ecology | |
| Remarks : | In the absence of specific environmental data for this product, this assessment is based on information for representative substances. |
13. DISPOSAL CONSIDERATIONS
| Waste disposal : | Product is suitable for burning for fuel value in compliance with applicable laws and regulations, and consideration of product characteristics at time of disposal. |
| Other regulations : | Disposal of unused product may be subject to RCRA regulations (40 CFR 261). Disposal of the used product may also be regulated due to ignitability, corrosivity, reactivity, or toxicity as determined by the Toxicity Characteristic Leaching Procedure (TCLP). |
| Flash Point : | > 55 °C (ASTM D-93) |
14. TRANSPORT INFORMATION
| Note : | The flash point of this material is > 55 °C, and hence regulatory classifications for flammability may vary. |
In accordance with 49 CFR 173.150(f)(2), non-bulk quantities of this material ( may be shipped as non regulated for USA domestic shipments.
ADR
| Proper shipping name : | GAS OIL |
| UN number : | 1202 |
| DOT ERG number : | 128 |
| Class : | 3 |
| Letter : | F |
| Packing group : | III |
| Labelling number : | 3 |
| Placard : | Flammable |
CFR
| Proper shipping name : | GAS OIL |
| UN number : | 1202 |
| DOT ERG number : | 128 |
| Class : | 3 |
| Letter : | F |
| Packing group : | III |
| Labelling number : | 3 |
| Placard : | Combustible |
IATA_C
| Proper shipping name : | GAS OIL |
| UN number : | 1202 |
| DOT ERG number : | 128 |
| Class : | 3 |
| Letter : | F |
| Packing group : | III |
| Labelling number : | 3 |
| Placard : | Flammable |
IMD
| Proper shipping name : | GAS OIL |
| UN number : | 1202 |
| DOT ERG number : | 128 |
| Class : | 3 |
| Letter : | F |
| Packing group : | III |
| Labelling number : | 3 |
| Placard : | Flammable |
| Marine pollutant : | Marine pollutant |
| Medical First Aid Guide : | 311 |
| (MFAG) table | |
| Emergency Schedule (EmS) number : |
3-07 |
| IMDG code page number : | 3375 |
| Static Accumulator (50 picosiemens or less) : |
Yes |
15. REGULATORY INFORMATION
| US OSHA Hazard Communication Standard : |
Product assessed in accordance with OSHA 29 CFR 1910.1200 and determined to be hazardous. |
| Governmental Inventory Status : |
All components comply with TSCA, EINECS/ELINCS, AICS, METI, DSL, KECI, ENCS, PICCS and IECSC. |
| EU Labelling : | Product is dangerous as defined by the European Union Dangerous Substances/Preparations Directives. |
| Symbols : | F, T, N Flammable, Toxic, Dangerous for the environment |
| R-Phrase(s) : | R10, R40, R65, R66, R51/53 |
| Flammable., Limited evidence of a carcinogenic effect., Harmful: may cause lung damage if swallowed., Repeated exposure may cause skin dryness or cracking., Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. | |
| S-phrase(s) : | S24, S2, S36/37, S62 |
| Avoid contact with the skin., Keep out of the reach of children., Wear suitable protective clothing and gloves., If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. | |
| Note : | Contains Gas Oil – unspecified. |
| SARA | |
| U.S. Superfund Amendments and Reauthorization Act SARA Title III : |
This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". |
| SARA (311/312) Reportable Hazard Categories : | Fire Chronic Acute |
| SARA (313) Toxic Release Chemicals : | Ethyl Benzene (100-41-4) – Conc < 1 %. |
The following product ingredients are cited on the lists below
| Chemical name | CAS-No. | Concentration [%] | List Citations |
| Diesel fuel | 68334-30-5 | > 98.00 | 21, 26 |
| Ethyl Benzene | 100-41-4 | < 1.00 | 1, 8, 10, 18, 19, 20, 21, 23, 24, 25, 26 |
| Naphthalene | 91-20-3 | < 1.00 | 16, 22 |
Regulatory List Searched
| 1 = ACGIH ALL | 6 = IARC 1 | 11 = TSCA 4 | 17 = CA P65 | 22 = MI 293 |
| 2 = ACGIH A1 | 7 = IARC 2A | 12 = TSCA 5a2 | 18 = CA RTK | 23 = MN RTK |
| 3 = ACGIH A2 | 8 = IARC 2B | 13 = TSCA 5e | 19 = FL RTK | 24 = NJ RTK |
| 4 = NTP CARC | 9 = OSHA CARC | 14 = TSCA 6 | 20 = IL RTK | 25 = PA RTK |
| 5 = NTP SUS | 10 = OSHA Z | 15 = TSCA 12b | 21 = LA RTK | 26 = RI RTK |
Code Key: CARC = Carcinogen; SUS = Suspected Carcinogen
16. OTHER INFORMATION
Note: Engen products do not contain PCBs.
Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for any other applications. In any case, the following advice should be considered:
INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a doctor as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
Precautionary Label Text:
CONTAINS DIESEL OIL.. C9-20
WARNING!
COMBUSTIBLE LIQUID AND VAPOUR. RESPIRATORY IRRITATION, HEADACHE, DIZZINESS, NAUSEA, LOSS OF CONSCIOUSNESS, AND IN CASES OF EXTREME EXPOSURE, POSSIBLY DEATH. LOW VISCOSITY MATERIAL-IF SWALLOWED, MAY BE ASPIRATED AND CAN CAUSE SERIOUS OR FATAL LUNG DAMAGE.
MAY CAUSE SKIN CANCER ON PROLONGED, REPEATED SKIN CONTACT. ANIMAL SKIN ABSORPTION STUDIES RESULTED IN INCREASED MORTALITY, EFFECTS ON BODY WEIGHT, THE IMMUNE SYSTEM AND THE UNBORN CHILD. PROLONGED, REPEATED SKIN CONTACT MAY CAUSE IRRITATION. DIESEL FUMES MAY CAUSE LUNG CANCER.
SAFETY: Keep away from heat and flame. Avoid prolonged or repeated overexposure by skin contact or inhalation. Use with adequate ventilation. Keep container closed. Keep out of reach of children.
FIRST AID: If inhaled, remove from further exposure. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. In case of contact, remove contaminated clothing. Dry wipe the exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself and others. Wear impervious gloves. If swallowed, seek immediate medical attention. Do not induce vomiting. Only induce vomiting at the instruction of a doctor.
This warning is given to comply with California Health and Safety Code 25249.6 and does not constitute an admission or a waiver of rights. This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. Chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm are created by the combustion of this product. Refer to product Material Safety Data Sheet for further safety and health information.
Disclaimer
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and we expressly disclaim all warranties of every kind and nature, including warranties of merchantability and fitness for a particular purpose in respect to the use or suitability of the product. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.
| Prepared by : | Product Safety Adviser |
| Health, Safety, Environment and Quality Department Engen Petroleum Limited P.O.Box 35, Cape Town, 8000 |
|
| Telephone : | (021) 403 4805 / 4911 (Office Hours) (021) 403 4099 (After Hours) 083 628 4415 (Cellular) |